Transition from Hund's coupling case (a) to case (b) in CaF (A((2)Pi(Omega))), obtained from the Ca(P-3(J))+CF2Cl2 -> CaF(A((2)Pi(Omega)))+CFCl2 reaction, induced by collisional energy

Pino GA; Rinaldi CA; Ferrero JC

Chemical Physics Letters, Vol.349, No.5-6, 463-470, 2001

DOI10.1016/S0009-2614(01)01258-1 Export Citation

Transition from Hund's coupling case (a) to case (b) in CaF (A((2)Pi(Omega))), obtained from the Ca(P-3(J))+CF2Cl2 -> CaF(A((2)Pi(Omega)))+CFCl2 reaction, induced by collisional energy

Pino GA, Rinaldi CA, Ferrero JC

The emission spectra of CaF A((2)Pi (Omega)) produced in the Ca(P-3(J)) + CF2Cl2 --> CaF(A ((2)Pi (Omega))) + CFCl2 reaction has been measured at two different collision energies, showing evidence for transition from Hund's coupling case (a) at the lower collision energy to case (b) at the higher one.