Chemical Physics Letters, Vol.366, No.3-4, 383-389, 2002
Comparison of CRDS to ICL-PAS and phase-shift CRDS spectroscopies for the absolute intensities of C-H (Delta upsilon(CH)=6) overtone absorptions
Cavity ring-down spectroscopy (CRDS) has been used to obtain the visible overtone spectra (Deltanu(CH) = 6) of neopentane, C(CH3)(4), propane, C3H8, and n-butane, C4H10, yielding absolute f-values for the transitions to better than 3%. For the neo-pentane overtone intensity, comparison with a recent measurement using intra-cavity laser photoacoustic spectroscopy (ICL-PAS) provides favourable agreement, with improved precision. Being absolute this value may be used as a standard for relative intensity measurements obtained by ICL-PAS. The measured propane and n-butane overtone intensities, when compared to recent work using phase-shift CRDS, indicate a lack of agreement to quoted uncertainties. (C) 2002 Elsevier Science B.V. All rights reserved.