Chemical Physics Letters, Vol.390, No.1-3, 55-58, 2004
Disappearing of the Verwey transition in magnetite nanoparticles synthesized under a magnetic field: implications 141 for the origin of charge ordering
It is observed that Fe3O4 nanoparticles exhibit a Verwey transition at approximately 120 K, in agreement with that observed in the corresponding bulk sample. While, the transition vanishes in the Fe3O4 nanoparticles formed under a 0.25 T magnetic field. It is found that the magnetic field induced oxidation of part of the Fe2+ ions on octahedral sites from lower spin states to higher spin states (Fe3+) during the formation of the nanoparticles, and then resulted in the vanishing of charge ordering between Fe2+ and Fe3+ on the octahedral sites below Verwey transition temperature (T-V) due to lacking of Fe2+ in some layers. (C) 2004 Elsevier B.V. All rights reserved.