화학공학소재연구정보센터
Chemical Physics Letters, Vol.397, No.1-3, 67-72, 2004
Magnetic resonance imaging of a magnetic field-dependent chemical wave
The magnetic field dependence of the travelling wave formed during the reaction of (ethylenediaminetetraacetato)cobalt(II) (Co(II)EDTA(2-)) and hydrogen peroxide was studied using magnetic resonance imaging (MRI). The reaction was investigated in a vertical tube, in which the wave was initiated from above. The wave propagated downwards, initially with a flat wavefront before forming a finger. Magnetic field effects were observed only once the finger had formed. The wave propagation was accelerated by a magnetic field with a negative gradient (i.e., when the field was stronger at the top of the tube than at the bottom) and slightly decelerated by positive field gradients. (C) 2004 Elsevier B.V. All rights reserved.