화학공학소재연구정보센터
Chemical Physics Letters, Vol.397, No.4-6, 368-373, 2004
Microscopic description of a liquid-vapor interface by an inhomogeneous integral equation theory
We developed an inhomogeneous integral equation theory yielding the inhomogeneous pair correlation functions as well as the density profiles of the liquid-vapor interface of simple fluid. We analytically derived the long-range asymptotics of the inhomogeneous pair distribution along the interface, related to capillary waves. We showed that their physical nature is the same as long-range fluctuations of critical fluid which are restricted to the two-dimensional interfacial region by the external field shaping the interface. (C) 2004 Elsevier B.V. All rights reserved.