The kinetics of the recombination reaction FSO2 + FSO3 -> FS(O-2)O(O-2)SF has been studied at 298 K. Both radicals were generated by 193-nm laser flash photolysis of FS(O-2)O(O-2)SF at total CO pressures ranging from 130 to 800 mbar. The decay of FSO3 radical was monitored by absorption spectroscopy at 450 nm. In all conditions, the reaction was found to be very close to the seeond-order regime being the limiting high-pressure rate coefficient (6.5 +/- 1.1) x 10(-11) cm(3) molecule(-1) s(-1). This value agrees very well with 7.7 x 10(-11) cm(3) molecule(-1) s(-1), as derived from statistical adiabatic channel model/classical trajectory calculations oil an electronic potential obtained from density functional theory calculations. (c) 2005 Elsevier B.V. All rights reserved.