Cavity ringdown spectroscopy of the (A)over-tilde-(X)over-tilde electronic transition of the phenyl peroxy radical

Just GMP; Sharp EN; Zalyubovsky SJ; Miller TA

Chemical Physics Letters, Vol.417, No.4-6, 378-382, 2006

DOI10.1016/j.cplett.2005.10.036 Export Citation

Cavity ringdown spectroscopy of the (A)over-tilde-(X)over-tilde electronic transition of the phenyl peroxy radical

Just GMP, Sharp EN, Zalyubovsky SJ, Miller TA

Cavity ringdown spectra (CRDS) of the near IR (A) over tilde (2) A'-(X) over tilde (2)A" electronic transition of phenyl peroxy radical are reported. The electronic origin is observed at 7497 cm(-1). Ab initio calculations have been carried out to aid the assignment of the electronic origin and other bands involving vibrational excitation. (c) 2005 Elsevier B.V. All rights reserved.