화학공학소재연구정보센터
Chemical Physics Letters, Vol.430, No.4-6, 282-286, 2006
Electronic spectroscopy of para-fluorotoluene clusters
We report (1 + 1) resonance-enhanced multiphoton ionization spectra for clusters of para-fluorotoluene (pFT)(n) (n = 1-11). After n = 2, the spectra appear to have converged in appearance, suggestive of a dimer chromophore, with weak bonding for subsequent additions of pFT molecules. The spectra also indicate dramatic, vibrational-mode-sensitive changes of oscillator strength between the monomer and the clusters. We also briefly describe the results of probing different parts of the expansion, and varying the laser power. (c) 2006 Elsevier B.V. All rights reserved.