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Chemical Physics Letters, Vol.436, No.4-6, 303-307, 2007
Far infrared stimulated emission from the 8s and 8f Rydberg states of NO
Directional light emission of NO in the far infrared region has been analyzed. Two main stimulated emission channels around 27 mu m (approximate to 11 THz) and 14 mu m for the 8s sigma(2)Sigma(+)(V = 0) level have been identified as the 8s sigma -> 7p sigma and 8s sigma -> 6f transitions, respectively. Two dominant band systems around 19 and 21 pin for the 815(v = 0) complex have been assigned to the 8f -> 7g and 8f -> 7d sigma transitions, respectively. The possibility of the black body induced transitions is briefly discussed. (c) 2007 Elsevier B.V. All rights reserved.