We report the geometries of two distorted T-shaped benzene dimer structures optimized at the RI-MP2/aug-cc-pVTZ level of theory. At the extrapolated RI-MP2/aug-cc-pV(TQ)Z level, the Cs over atom and C-s over bond configurations were found to be lower in energy than the conventionally accepted G(2v) T-shaped structure by 0.146 and 0.163 kcal/mol, respectively. When Delta CCSD(T)/6-311 +G(2df,p) corrections were included, these structures remained lower in energy than the C,,, reference by 0. 127 and 0. 132 kcal/mol, respectively, with C, over bond as the minimum energy T-shaped structure. While not the focus of this Letter, we also report that the C-2v T-shaped configuration is stabilized by 0.31 kcal/mol over the C-2h parallel-displaced configuration at the ACCSD(T)/aug-cc-pVTZ approximation to the CCSD(T)/CBS limit. (c) 2007 Elsevier B.V. All rights reserved.