Chemistry Letters, Vol.29, No.11, 1274-1275, 2000
A novel organic conductor with three-dimensional molecular array: (TM-TPDS)(2)AsF6
The title material, where TM-TPDS is 2-[4,5-bis(methylthio)-1,3-diselenol-2-ylidene]-5-(thiopyran-4-ylidene)-1,3,4,6-tetrathiapentalene, has three-dimensional (3D) donor array, in which 1D donor columns are tetragonally arranged with each other. It shows metal-like conducting behavior down to T-MI = 100 K.