Chemistry Letters, Vol.30, No.1, 74-75, 2001
New low-temperature synthetic method of complex inorganic solids: Amorphous route based on amorphous nature of soluble giant clusters
The amorphous nature of molybdenum giant clusters (molybdenum blue species) was used to prepare compositionally well-arranged precursors (homogeneous amorphous phase), which are suitable for lower temperature syntheses of alkalimetal molybdenum oxide bronzes. Then, it was confirmed that soluble giant clusters such as molybdenum blue species afforded very attractive merits for materials syntheses.