Chemistry Letters, Vol.31, No.3, 346-347, 2002
Chiral crystallization of a linear two-coordinated palladium(0) complex bearing propeller-shaped bulky phosphine ligands
A linear bis(phosphine) palladium(0) complex with the bulky aryl substituent, tris(2,2",6,6"-tetramethyl-m-terphenyl-5'-yl (Tmtp), was found to crystallize as a spontaneously resolved homochiral clathrate with toluene molecules.