Chemistry Letters, Vol.31, No.10, 1000-1001, 2002
Synthesis and crystal structures of [CuCl2(mu-NSPh3)](2) and [CuCl2(Ph3SN)(2)]: Novel copper complexes bearing organic lambda(6)-sulfanenitrile as ligand
Dinuclear complex [CuCl2(mu-NSPh3)](2) (2) and mononuclear complex [CUCl2(Ph3SN)(2)] (3) were obtained concurrently by a reaction Of CUCl2 with triphenyl-lambda(6)-sulfanenitrile (1) in acetonitrile. They were characterized by elemental analysis, IR and NMR spectroscopy, and their molecular structures were determined by X-ray crystallographic analysis.