Unprecedented soliton formation mechanism in quasi-one-dimensional chloro-bridged Pt-II-Pt-IV mixed-valence compound, {[Pt(en)(2)][PtCl2(en)(2)]}(3)(CuCl4)(4)center dot 12H(2)O

Yamashita M; Aso H; Matsunaga S; Takizawa K; Nakata K; Kachi-Terajima C; Iwahori F; Ishii T; Miyasaka H; Sugiura K; Kawashima T; Takai K; Kuroda N; Shiro M; Kishida H; Okamoto H; Takahashi H; Tanaka H; Marumoto K; Kuroda S

Chemistry Letters, Vol.32, No.3, 278-279, 2003

DOI10.1246/cl.2003.278 Export Citation

Unprecedented soliton formation mechanism in quasi-one-dimensional chloro-bridged Pt-II-Pt-IV mixed-valence compound, {[Pt(en)(2)][PtCl2(en)(2)]}(3)(CuCl4)(4)center dot 12H(2)O

Yamashita M, Aso H, Matsunaga S, Takizawa K, Nakata K, Kachi-Terajima C, Iwahori F, Ishii T, Miyasaka H, Sugiura K, Kawashima T, Takai K, Kuroda N, Shiro M, Kishida H, Okamoto H, Takahashi H, Tanaka H, Marumoto K, Kuroda S

A new type of complex consisting of double liner-chain structure {[Pt(en)(2)][PtCl2(en)(2)]}(3)(CuCl4)(4) . 12H(2)O was synthesized. High concentration (ca. 200 times larger than the literature) of neutral soliton (Pt-III component) formation was found. This unprecedented soliton formation mechanism will be discussed.