Spin crossover complex film, [Fe-II(H-trz)(3)]-nafion, with a spin transition around room temperature

Nakamoto A; Ono Y; Kojima N; Matsumura D; Yokoyama T

Chemistry Letters, Vol.32, No.4, 336-337, 2003

DOI10.1246/cl.2003.336 Export Citation

Spin crossover complex film, [Fe-II(H-trz)(3)]-nafion, with a spin transition around room temperature

Nakamoto A, Ono Y, Kojima N, Matsumura D, Yokoyama T

We have synthesized [Fe-II(H-trz)(3)](n) complex film by using ion-exchange resin(Nafion) as counter anion, and have found the spin crossover phenomenon about at 260 K. Moreover, we have proved the existence of straight one-dimensional Fe chain structure of [Fe-II(H-trZ)(3)](n) on Nafion by means of EXAFS.