Crystal structure of [(C2H5)(2)(CH3)(2)N][Pd(dmit)(2)](2) at high pressure

Okano Y; Adachi T; Narymbetov B; Kobayashi H; Zhou B; Kobayashi A

Chemistry Letters, Vol.33, No.7, 938-939, 2004

DOI10.1246/cl.2004.938 Export Citation

Crystal structure of [(C2H5)(2)(CH3)(2)N][Pd(dmit)(2)](2) at high pressure

Okano Y, Adachi T, Narymbetov B, Kobayashi H, Zhou B, Kobayashi A

The high-pressure crystal structure determination was performed on [(C2H5)(2)(CH3)(2)N][Pd(dmit)(2)](2), which is a unique molecular superconductor with pressure-induced insulating phase above about 7 kbar. The structure analysis at 10 kbar revealed the pressure-induced cation ordering coupled with the doubling of the unit cell.