Chemistry Letters, Vol.33, No.10, 1322-1323, 2004
A study on the electronic effect of reactions of pi-allylpalladiums using 2-arylsulfonyloxy-3-chloropropenes with ethyl malonate and their synthetic utilization
We have studied in detail the electronic effect on the reactions of pi-allylpalladium with nucleophiles during the reactions of 2-arylsulfonyloxy-3-chloroprop-1-ene with diethyl malonate. The reaction rates increase increasing with the electron-withdrawing effects. We have also shown some synthetic utilization using these 2-arylsulfonyloxyprop-1-enes.