Cyclic diaminocarbene-rhodium(I) complex tethered to disulfide: Synthesis and application to gold surface modification

Hara K; Iwahashi K; Kanamori Y; Naito S; Takakusagi S; Uosaki K; Sawamura M

Chemistry Letters, Vol.35, No.8, 870-871, 2006

DOI10.1246/cl.2006.870 Export Citation

Cyclic diaminocarbene-rhodium(I) complex tethered to disulfide: Synthesis and application to gold surface modification

Hara K, Iwahashi K, Kanamori Y, Naito S, Takakusagi S, Uosaki K, Sawamura M

A dimeric N-heterocyclic carbene (NHC)-rhodium(I) complex connected with a long chain dialkyl disulfide linker was synthesized, and used for the preparation of a Rh-modified alkane thiolate monolayer on a gold surface.