Disproportionation reaction of seven-coordinate [(ReO)-O-V(tpen)](3+) into [(ReO)-O-IV(tpen)](2+) and [Re-VII(O)(3)(tpenH-kappa(3) N,N'',N''')](2+) where tpen is N,N,N,N'-tetrakis(2-pyridylmethyl)ethylenediamine

Tabeya T; Abe M; Sasaki Y

Chemistry Letters, Vol.35, No.9, 1066-1067, 2006

DOI10.1246/cl.2006.1066 Export Citation

Disproportionation reaction of seven-coordinate [(ReO)-O-V(tpen)](3+) into [(ReO)-O-IV(tpen)](2+) and [Re-VII(O)(3)(tpenH-kappa(3) N,N'',N''')](2+) where tpen is N,N,N,N'-tetrakis(2-pyridylmethyl)ethylenediamine

Tabeya T, Abe M, Sasaki Y

UV-vis and H-1 NMR spectra provide unambiguous evidences for the disproportionation reactions of ((ReO)-O-V(tpen)](3+) to give [(ReO)-O-IV(tpen)](2+) and [Re-VII(O)(3)(tpenH-kappa(3) N,N",N''')](2+) (tpen = N,N,N',N'-tetrakis(2-pyridyimethyl)ethylenediamine) in 2:1 ratio with the important participation of water molecules.