Synthesis of beta-amino acid derivatives by nickel(0)-mediated sequential addition of carbon dioxide and dibenzoyldiazene onto unsaturated hydrocarbons

Murakami M; Ishida N; Miura T

Chemistry Letters, Vol.36, No.3, 476-477, 2007

DOI10.1246/cl.2007.476 Export Citation

Synthesis of beta-amino acid derivatives by nickel(0)-mediated sequential addition of carbon dioxide and dibenzoyldiazene onto unsaturated hydrocarbons

Murakami M, Ishida N, Miura T

A stoichiometric amount of nickel(0) complex mediated the aminative carboxylation of unsaturated hydrocarbons through oxidative cyclization with carbon dioxide followed by insertion of dibenzoyldiazene into the carbon-nickel bond, giving beta-amino acid derivatives.