Rh3+ and Rh3+-diamine complexes intercalated in gamma-titanium hydrogen phosphate. Synthesis, characterisation and catalytic activity towards aniline oxidative carbonylation processes

Giannoccaro P; De Giglio E; Gargano M; Aresta M; Ferragina C

Journal of Molecular Catalysis A-Chemical, Vol.157, No.1-2, 131-141, 2000

DOI10.1016/S1381-1169(99)00425-2 Export Citation

Rh3+ and Rh3+-diamine complexes intercalated in gamma-titanium hydrogen phosphate. Synthesis, characterisation and catalytic activity towards aniline oxidative carbonylation processes

Giannoccaro P, De Giglio E, Gargano M, Aresta M, Ferragina C

New materials containing Rh(III) ions or Rh(III)-diamine complexes [(L = 2,2'-bipyridyl (bipy); 1,10-phenanthroline (phen); 2,9-dimethyl-1,10-phenanthroline (dmp)] intercalated in gamma-titanium phosphate (gamma-TiP) are described. The compounds have formula gamma-TiPHxRhy. tH(2)O (x= 2-3y; 0

Keywords:reductive carbonylation;carbamates;N,N '-diphenylurea;rhodium-supported;heterogeneous catalysis;titanium hydrogen phosphate;intercalation compounds