The demand for effective and inexpensive adsorbents is to increase in response to the widespread recognition of the deleterious health effects of arsenic exposure through drinking water. A novel adsorbent, aluminum-loaded Shirasu-zeolite P-1 (Al-SZP(1)), was prepared and employed for the adsorption and removal of arsenic(V) (As(V)) ion from aqueous system. The process of adsorption follows first-order kinetics and the adsorption behavior is fitted with a Freundlich isotherm. The adsorption of As(V) is slightly dependent on the initial pH over a wide range (3-10). Al-SZP(1) was found with a high As(V) adsorption ability, equivalent to that of activated alumina, and seems to be especially suitable for removal of As(V) in low concentration. The addition of arsenite, chloride, nitrate, sulfate, chromate, and acetate ions hardly affected the As(V) adsorption, whereas the coexisting phosphate greatly interfered with the adsorption. The adsorption mechanism is supposed as a ligand-exchange process between As(V) ions and the hydroxide groups present on the surface of Al-SZP(1). The adsorbed As(V) ions were desorbed effectively by a 40 mM NaOH solution. Continuous operation was demonstrated in a column packed with Al-SZP(1). The feasibility of this technique to practical utilization was also assessed by adsorption/desorption multiple cycles with in situ desorption/regeneration operation. (C) 2002 Elsevier Science B.V. All rights reserved.