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Journal of Hazardous Materials, Vol.142, No.1-2, 564-567, 2007
Pseudo-second order models for the adsorption of safranin onto activated carbon: Comparison of linear and non-linear regression methods
Kinetic experiments were carried out for the sorption of safranin onto activated carbon particles. The kinetic data were fitted to pseudo-second order model of Ho, Sobkowsk and Czerwinski, Blanchard et al. and Ritchie by linear and non-linear regression methods. Non-linear method was found to be a better way of obtaining the parameters involved in the second order rate kinetic expressions. Both linear and non-linear regression showed that the Sobkowsk and Czerwinski and Ritchie's pseudo-second order models were the same. Non-linear regression analysis showed that both Blanchard et al. and Ho have similar ideas on the pseudo-second order model but with different assumptions. The best fit of experimental data in Ho's pseudo-second order expression by linear and non-linear regression method showed that Ho pseudo-second order model was a better kinetic expression when compared to other pseudo-second order kinetic expressions. (c) 2006 Published by Elsevier B.V.
Keywords:adsorption;safranin;activated carbon;pseudo-second order kinetics;linear regression;non-linear regression