화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.83, No.4, 841-847, 2000
Superplastic behavior of fine-grained beta-silicon nitride material under compression
The deformation behavior of a hot-pressed, fine-grained beta-Si3N4 ceramic was investigated in the temperature range 1450 degrees-1650 degrees C, under compression, and the results for strain rate and temperature dependence of the flow stress are presented here. The present results show that the material is capable of high rates of deformation (similar to 10(-4)-10(-3) s(-1)) within a wide range of deformation temperatures and under a pressure of 5-100 MPa; no strain hardening occurs in the material, even at slow deformation rates, because of its stable microstructure; Newtonian flow occurs, with a stress exponent of approximately unity; and the material has activation energy values for flow in the range 344-410 kJ . mol(-1). Grainboundary sliding and grain rotation, accommodated by viscous flow, might be the mechanisms of superplasticity for the present material.