AIN-SiC solid solutions were synthesized via a combustion nitridation process. Reactions between powder mixtures of aluminum, silicon, and carbon or aluminum with beta-SiC and gaseous nitrogen under pressures of 0.1-8.0 MPa are self-sustaining once they have been initiated. Investigations were made with reactant ratios of Al:Si:C = 7:3:3, 6:4:4, and 5:5:5 and Al:Si:C = 7:3, 6:4, and 5:5, For the AI-Si-C system (molar ratio of 6:4:4), the maximum combustion temperature was dependent on the nitrogen pressure, increasing from 2300 degrees C to 2480 degrees C with an increase in pressure, from 0.1 MPa to 6.0 MPa, In all cases, the product contained the solid solution as the primary phase, with minor amounts of silicon. The amount of unreacted silicon decreased as the nitrogen pressure increased; the presence and dependence of unreacted silicon on pressure has been explained in terms of the volatilization of aluminum. The full width at half maximum for the (110) peak of the AIN-SiC solid solution decreased as the nitrogen pressure increased, which indicated the formation of a more homogeneous product.