The opportunities are introduced to calculate the electrical, mechanical, and thermal couplings of ceramic multilayer capacitors (MLCs) with the finite-element method. The results may lead to improvements in the production, integration, and operation of MLCs. In this paper, a comparison is given of calculations and measurements of electrochemical resonances in the impedance spectra of MLCs. The simulation of defective capacitors with three different types of assumed faults reveals the changes in the impedance spectra due to these defects. This allows the prediction of flaws in MLCs based on measurement of the impedance spectra.