화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.84, No.8, 1822-1826, 2001
Compressive creep performance of SrFeO3
Compressive creep performance of strontium-deficient and strontium-excess SrFeO3-delta materials has been investigated in the temperature range 800 degrees -1000 degreesC and in the stress range 2.5-25 MPa. The absolute densities of the strontium-deficient and strontium-excess materials are 4.99 and 5.25 g/cm(3), respectively, which corresponds to porosities of similar to2% and 5%, respectively. Both materials contain secondary phases because of the cation nonstoichiometry. The creep rate is faster for the strontium-deficient material than the strontium-excess material. The stress exponent is approximately unity, and the activation energy is 260 +/- 30 kJ/mol for both materials. The results can be explained by a cation diffusion mechanism. The present findings are discussed in relation to previous sintering data and the possible application of these materials as oxygen-permeable membranes.