Fluoroapatite/hydroxyapatite (FA/HA) solid solution shows good bioactivity and stability, and is one of promising biomaterials. In this work, 1.67Ca(NO3)(2)-PO(OEt)(x)(OH)(3-x) ethanol solutions with different concentrations of trifluoroacetic acid and triethanolamine were mixed. The mixed solutions were transformed into the as-prepared powder on a hot plate. After the as-prepared powder was calcined at 500 or 900degreesC, a pure FA/HA phase could be obtained. The fluorine contents in the FA/HA strongly depended on the ratios of triethanolamine/trifluoroacetic acid. The presence of triethanolamine in the mixed solutions enhances the dissociation of trifluoroacetic acid and accelerates the formation of unevaporable Ca(OOCF3C)(x) (NO3)(2-x) complex species, as a result, more fluorine could be incorporated into the apatite to form the solid solution. (C) 2002 Elsevier Science B.V. All rights reserved.