In this study, sodium titanium phosphate, NaTi2(PO4)(3) was synthesized in a pure form by using microwave energy. The NaTi2(PO4)(3) was obtained by mixing the initial reactants of TiO2, (NH4)(2)HPO4 and NaH2PO4-2H(2)O with the molar ratio of 2:2:1 in a domestic type of microwave oven by using 2.45 GHz frequencies and at power of 750 W. The reaction was completed in 15 min. The microwave heating process was achieved by the help of the NaH2PO4-2H(2)O which is the only microwave absorber in the initial mixture. The product was analyzed by X-ray diffraction (XRD) and fourier transform infra red (Fr-IR) techniques and the results confirms the rhombohedral crystal structure of the NaTi2(PO4)3 With the unit cell parameters of a = 8.4913(3), c = 21.7858(12) angstrom, space group R (3) over barc and Z:6. The titled compound is also known as a member of NASICON materials. In future, it is possible to synthesize different types of sodium including NASICON compounds by the help of microwave susceptor agent of the NaH2C4 center dot 2H(2)O. (c) 2005 Elsevier B.V. All rights reserved.