Journal of Crystal Growth, Vol.246, No.3-4, 259-270, 2002
Comparison between structural properties of bulk GaN grown in liquid Ga under high N pressure and GaN grown by other methods
In this paper defects formed in GaN grown by different methods are reviewed. Formation of particular defects are often related to the crystallographic direction in which the crystals grow. For bulk crystals the highest growth rates are observed for directions perpendicular to the c-axis. Threading dislocations and nanopipes along the c-axis are not formed in these crystals, but polarity of the growth direction plays a role concerning defects that are formed and surface roughness. For growth of homoepitaxial layers, where growth is forced to take place in the c-direction threading dislocations are formed and their density is related to the purity of constituents used for growth and to substrate surface inhomogeneities. In heteroepitaxial layers two other factors: lattice mismatch and thermal expansion mismatch are related to the formation of dislocations. Doping of crystals can also lead to the formation of defects characteristic for a specific dopant. This type of defects tends to be growth method independent but can depend on growth polarity. (C) 2002 Elsevier Science B.V. All rights reserved.
Keywords:defects;magnesium doping;transmission electron microscopy;bulk;hydride vapor phase epitaxy;homoepitaxial and heteroepitaxial gallium nitride