The phase diagrams of phenothiazine with each of in-nitrobenzoic acid (m-NBA) and m-dinitroberizene (m-DNB) have been studied by thaw-melt method. These materials have been characterized by X-ray diffraction. Growth behavior of the parent components, eutectic and charge transfer complex (CTC) studied by measuring the rate of movement of the growth front in a capillary suggests the applicability of Hillig-Turnbull equation for the system. Microstructure and electrical conductivities of congruent melting complexes and eutectics have been determined. The low electrical conductivities of these materials have been due to weak interaction and mixed stacking of donor and acceptor. Excess thermodynamics functions of the charge-transfer (CT) materials and eutectics have been determined. (c) 2007 Elsevier B.V. All rights reserved.