화학공학소재연구정보센터
Polymer(Korea), Vol.10, No.6, 635-640, October, 1986
유연격자 양단에 메소겐기를 갖고 있는 열방성화합물, 디메소겐성 네마틱 화합물과 네마틱 혹은 콜레스테릭 폴리에스테르의 혼합성
Thermotropic Compounds having Two Terminal Mesogenic Units and Central Spacers. 9. Miscibility between Dimesogenic, Nematic Compounds and Nematic or Cholesteric Polyesters
Miscibility of dimesogenic, nematic, compounds with main chain nematic or cholesteric polymers having flexible spacers was examined by differential scanning calorimetry on a polarizing microscope. The four pairs studied in the present investigation revealed complete miscibility in mesophases. In solid state, however, they showed more complicated behavior. When the structures of a polymer and a dimesogenic compound were similar, eutectic formation was observed. No eutectic formation was detected when the structures of the pair were not similar. The Schr der-van Laar equation melting temperatures only for two systems among the four pairs of mixtures studied.