The influence of the pulse duration on the laser-induced changes in a thin triazenepolymer film on a glass substrate has been investigated for single, near-infrared (800 nm) Ti:sapphire laser pulses with durations ranging from 130 fs up to 2.6 ps. Postirradiation optical microscopy has been used to quantitatively determine the damage threshold fluence. The latter decreases from similar to 800 mJ/cm(2) for a 2.6 ps laser pulse to similar to 500 mJ/cm(2) for a pulse duration of 130 fs. In situ real-time reflectivity (RTR) measurements have been performed using a ps-resolution streak camera set-up to study the transformation dynamics upon excitation with single pulses of duration of 130 fs and fluences close to the damage threshold. Very different reflectivity transients have been observed above and below the damage threshold fluence. Above the damage threshold, an extremely complicated behaviour with oscillations of up to 100% in the transient reflectivity has been observed. Below the damage threshold, the transient reflectivity decreases by as much as 70% within 1 ns with a subsequent recovery to the initial level occurring on the ms timescale. No apparent damage could be detected by optical microscopy under these irradiation conditions. Furthermore, within the 395-410 mJ/cm(2) fluence range, the transient reflectivity increases by similar to 10%. The analysis of these results indicates that the observed transformations are thermal in nature, in contrast to the known photochemical decomposition of this triazenepolymer under UV irradiation. (c) 2005 Elsevier B.V. All rights reserved.