The synthesis of the high-pressure F phase of iron was attained using a femtosecond laser. The crystalline structure in a recovered iron sample was determined using electron diffraction and synchrotron X-ray diffraction methods. The high-temperature gamma phase of iron also existed in the recovered sample. The temperature inside the shock front was calculated using thermodynamic equations. It was found that the E; phase was induced by the shock itself but not the gamma phase. The gamma phase was suggested to be induced as an intermediate structure between the alpha-epsilon transition. The femtosecond laser driven shock may have the potential to synthesis high-pressure phases, which has not been attained using conventional methods. (c) 2005 Elsevier B.V All rights reserved.