Polymer(Korea), Vol.11, No.2, 108-111, April, 1987
농축용액에서 막대형 고분자의 회전 확산계수
Rotational Diffusivity of Rod-Like Macromolecule in Concentrated Solution
Rotational diffusivity of rod-like macromolecules in concentrated solutions is severely affected by the entanglement of those molecules. The kinetic theory to describe this effect is recaptured to include the side wall effect of the test rod argument of Doi, which fumed out to be very important in case of strong extensional flow. The initial relaxation time τ1 of the Kerr effect depends on the concentration ρ and the molecular weight M such that τ1 ∝ ρ Ms instead of ρ2M7 given by Doi. which is good for the relaxation time for the final stage.