화학공학소재연구정보센터
Applied Surface Science, Vol.253, No.15, 6465-6470, 2007
Assessing the effect of the matrix in resonant infrared MAPLE
The ablation yield of polyethylene glycol is measured as a function of laser pulse energy and polymer molecular weight for both free running and Q-switched Er:YAG lasers. The results show that the deposition rate is dependent on the absorption coefficient in a way that is consistent with the blow-off ablation model but that the linear dependence of the efficiency on laser pulse energy is also consistent with a steady-state ablation model. The results for both lasers are remarkably similar given that the pulse durations are 350 mu s and 85 ns, respectively. Furthermore, polystyrene thin films are deposited as well and it is found that the morphology depends on the THF/MeOH ratios in the matrices. The significance of these results is discussed as well as future directions for this research. (C) 2007 Elsevier B.V. All rights reserved.