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Macromolecular Rapid Communications, Vol.22, No.4, 274-280, 2001
Biodegradable polymers with specific metal binding sites based on bipyridine-containing poly(lactid acid) and Poly(epsilon-caprolactone): Towards high-molecular weight polyesters
Mono- and difunctionalized 6,6'-dimethyl-2,2'-bipyridines were introduced into polyesters in order to design polymer architectures with specific metal binding units. The polymerizations were carried out using aluminium-alkoxide derivatives prepared by a reaction between triethylaluminium and the corresponding hydroxymethyl-functionalized bipyridine derivatives. Polymers with narrow molecular weight distribution were obtained. The incorporation of the metal binding unit could be proven by UV/VIS-spectroscopy and NMR-spectroscopy.