Macromolecular Rapid Communications, Vol.25, No.19, 1708-1713, 2004
Variation of the effective activation energy throughout the glass transition
An advanced isoconversional method has been applied to determine the effective activation energies (E) for the glass transition in polystyrene (PS), poly(ethylene terephthalate) (PET), and boron oxide (B2O3). The values of E decrease from 280 to 120 kJ . mol(-1) in PS, from 1270 to 550 kJ mol(-1) in PET, and from 290 to 200 kJ mol(-1) in B2O3. It is suggested that a significant variation in E should be observed for the fragile glasses that typically include polymers.
Keywords:activation energy;differential scanning calorimetry (DSC);glass transition;isoconversional method;kinetics (polym.)