Reaction Kinetics and Catalysis Letters, Vol.71, No.2, 343-347, 2000
Kinetics and mechanism of the oxidative regeneration of carbonyl compounds from oximes by pyridinium fluorochromate
Oxidative deoximination of aldoximes and ketoximes by pyridinium fluorochromate proceeds by nucleophilic attack of the chromate oxygen on the oxime carbon to give a cyclic intermediate in the rate-determining step.