Reaction Kinetics and Catalysis Letters, Vol.76, No.2, 369-374, 2002
Kinetic equation for reversible heterogeneous catalytic reactions
It is demonstrated that when operating far from equilibrium, despite the nonlinearity of a complex reaction system, the overall rate of a heterogeneous catalytic reaction is expressed by a classical equation, where the equilibrium constant is determined by the ratio of constants of the forward and reverse reaction, which do not include the lateral interactions in the adsorbed layer.