Reaction Kinetics and Catalysis Letters, Vol.79, No.2, 357-364, 2003
Study of cesium phospho(vanado)molybdates active in the oxidative derydrogenation of cyclohexane
Cs2.5M0.08H0.26PMo12O40 and Cs2.5M0.08H1.26PMo11VO40 (M: Ni, Fe) heteopolyanions were selectively prepared, characterized by IR, Raman, P-31 NMR, XPS and XRD and tested in the ODH of cyclohexane. The salt structure, and reaction mechanism and kinetics are discussed.