Reaction Kinetics and Catalysis Letters, Vol.82, No.1, 65-71, 2004
Aminated MCM-41-tethered Wilkinson's complex: Active immobilized catalyst precursor for cyclohexene hydroformylation
A Wilkinson' complex-derived MCM-41-tethered catalyst via an amine ligand is fairly effective and stable for cyclohexene hydroformylation at 100degreesC and 28 bar of equimolar CO and H-2. This catalyst has the advantages of both high activity and resistance to rhodium leaching.