PET 섬유용 내구성 대전방지제에 관한 연구. 2. 아크릴 대전방지제에 의한 PET의 대전방지가공

박흥수; 김영근; 김준택; 배장순; 최희천

Polymer(Korea), Vol.14, No.3, 211-219, June, 1990

Export Citation

PET 섬유용 내구성 대전방지제에 관한 연구. 2. 아크릴 대전방지제에 의한 PET의 대전방지가공

Studies on the Durable Antistatic Agents for PET Fibers. 2. Antistatic Finish of PET by Acrylic Antistatic Agent

박흥수, 김영근, 김준택, 배장순, 최희천

초록

4차 2-dimethylaminoethylmethacrylate-N-methylolacrylamide 공중합체를 합성하고 이를 아크릴계 대전방지제의 모체수지로서 사용하였다. 여기에 높은 흡습성의 anhydrous lithium chloride와 sodium gluconate를 블렌딩시켜 내구성 대전방지제(ANTA)를 제조하였다. ANTA를 PET직물에 단독 혹은 수지병용으로 처리한 후 내세탁성 시험결과 ANTA-8과 ANTA-9는 낮은 표면저항,작은 값의 마찰대전압 및 짧은 반감기 값을 가지는 양호한 내구성 대전방지제임이 입증되었다.

Quaternized 2-dimethylaminoethylmethacrylate-N-methylolacrylamide copolymer was synthesized as a base resin of acrylic type antistatic agent. Anhydrous lithium chloride and sodium gluconate having high absorbency were blended with the copolymer to give durable antistatic agent (ANTA). Treatment with and without resin to PET textile revealed that the synthesized ANTA-8 and ANTA-9 were good durable antistatic agents having low surface resistance, small frictional voltage and short half-life of electric charge.

[References]

Hersh SP, Montgomery DJ, Text. Res. J., 25, 261 (1955)
Cunnigham RG, Montgomery DJ, Text. Res. J., 18, 971 (1958)
Hersh SP, Sharman EP, Text. Res. J., 24, 426 (1954)
Gonsalves VE, van Dongeren BJ, Text. Res. J., 24, 1 (1954)
Sugiyama SZ, Surface, 21, 36 (1983)
Ballow JW, Text. Res. J., 24, 146 (1954)
Henshall AE, J. Soc. Dyers Color, 76, 525 (1960)
Marumo H, Takai M, Saito M, Kogyo Kagaku Zasshi, 72, 940 (1969)
Barnes GT, Mod. Tex., 51, 45 (1970)
Wilson N, Text. Inst. Ind., 10, 235 (1972)
Mizutani T, Mitani K, Ieda M, Jpn. J. Appl. Phys., 22, 677 (1983)
Lewis DM, Text. Res. J., 54, 279 (1984)
Gardiner D, Holmes FH, J. Soc. Dyers Color, 83, 43 (1967)
Willson N, Text. J. Austr., 51, 10 (1976)
Kimura Y, Angew. Makromol. Chem., 132, 169 (1985)
Tambor M, Cope JL, Jerome JL, U.S. Patent, 4737156 (1988)
Maity NC, Kartha KPR, Srivastava HC, Colourage, 31, 11 (1984)
Park HS, Kim YG, Kim JT, Bea JS, Choi HC, Polym.(Korea), 14(2), 153 (1990)
Ganmo S, Kogyo Kagaku Zasshi, 69, 1504 (1966)
Takahara K, "Synthetic Design and New Use Development of Acrylic Resin," 1st ed., p. 40, Koubun Dou Co., Nagoyo (1985)
Balback G, Kunststoffe, 67, 154 (1977)
Rath H, Herbolsheimer E, Stapt S, Text. Res. J., 30, 201 (1960)
Marsh JT, "An Introduction to Textile Finishing," 1st ed., p. 247, Chapman & Hall Ltd., New York (1950)
Venkatesh GM, Das TK, Pal S, Atira Tech. Dig., 13, 4 (1979)
Ganmo S, Kogyo Kagaku Zasshi, 72, 940 (1969)
Holmes FH, Heap SA, J. Soc. Dyers Color, 83, 12 (1967)
Holmes FH, "Paper Presented at the Conference on Assessment and Elimination of Static Electricity on Textiles," 8th ed., p. 313, Shirley Institute, Manchester (1971)

[Referenced By]

[1] Hersh SP, Montgomery DJ, Text. Res. J., 25, 261 (1955)

[2] Cunnigham RG, Montgomery DJ, Text. Res. J., 18, 971 (1958)

[3] Hersh SP, Sharman EP, Text. Res. J., 24, 426 (1954)

[4] Gonsalves VE, van Dongeren BJ, Text. Res. J., 24, 1 (1954)

[5] Sugiyama SZ, Surface, 21, 36 (1983)

[6] Ballow JW, Text. Res. J., 24, 146 (1954)

[7] Henshall AE, J. Soc. Dyers Color, 76, 525 (1960)

[8] Marumo H, Takai M, Saito M, Kogyo Kagaku Zasshi, 72, 940 (1969)

[9] Barnes GT, Mod. Tex., 51, 45 (1970)

[10] Wilson N, Text. Inst. Ind., 10, 235 (1972)

[11] Mizutani T, Mitani K, Ieda M, Jpn. J. Appl. Phys., 22, 677 (1983)

[12] Lewis DM, Text. Res. J., 54, 279 (1984)

[13] Gardiner D, Holmes FH, J. Soc. Dyers Color, 83, 43 (1967)

[14] Willson N, Text. J. Austr., 51, 10 (1976)

[15] Kimura Y, Angew. Makromol. Chem., 132, 169 (1985)

[16] Tambor M, Cope JL, Jerome JL, U.S. Patent, 4737156 (1988)

[17] Maity NC, Kartha KPR, Srivastava HC, Colourage, 31, 11 (1984)

[18] Park HS, Kim YG, Kim JT, Bea JS, Choi HC, Polym.(Korea), 14(2), 153 (1990)

[19] Ganmo S, Kogyo Kagaku Zasshi, 69, 1504 (1966)

[20] Takahara K, "Synthetic Design and New Use Development of Acrylic Resin," 1st ed., p. 40, Koubun Dou Co., Nagoyo (1985)

[21] Balback G, Kunststoffe, 67, 154 (1977)

[22] Rath H, Herbolsheimer E, Stapt S, Text. Res. J., 30, 201 (1960)

[23] Marsh JT, "An Introduction to Textile Finishing," 1st ed., p. 247, Chapman & Hall Ltd., New York (1950)

[24] Venkatesh GM, Das TK, Pal S, Atira Tech. Dig., 13, 4 (1979)

[25] Ganmo S, Kogyo Kagaku Zasshi, 72, 940 (1969)

[26] Holmes FH, Heap SA, J. Soc. Dyers Color, 83, 12 (1967)

[27] Holmes FH, "Paper Presented at the Conference on Assessment and Elimination of Static Electricity on Textiles," 8th ed., p. 313, Shirley Institute, Manchester (1971)