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Electrochimica Acta, Vol.42, No.10, 1473-1480, 1997
A Numerical Approach to the Voltammograms of the Reduction of Prussian Blue Films on Ito Electrodes
The uncompensated resistance, mainly due to the ITO electrode, modifies the shape of voltammetric curves of the system Prussian Blue reversible arrow Everitt’s Salt films deposited on this transparent electrode. A numerical finite difference model which is able to explain the shape of these voltammetric curves is studied iii this paper. This model explains the dependence of voltammetric curves on the film thickness and uncompensated resistance.
Keywords:ELECTROCHEMICAL PREPARATION METHOD;IRON HEXACYANOFERRATE FILMS;LINEAR SWEEP VOLTAMMETRY;FINITE DIFFUSION SPACE;CYCLIC VOLTAMMETRY;POLYMER-FILMS;THIN-FILMS;POLY(VINYLFERROCENE);FE4(FE(CN)6)3.XH2O;OXIDATION