가황조건과 피복물질이 배합고무와 강선코드사이의 접착에 미치는 영향: 1. 황과 가황촉진제의 영향

서곤; 강신영; 박문우; 김재문; 김민호; 문재창

Polymer(Korea), Vol.15, No.3, 297-310, June, 1991

Effect of Cure Conditions and Coating Materials on Adhesion between Steel Cord and Rubber Compound : 1. Effect of Sulfur and Accelerator Contents

서곤, 강신영, 박문우, 김재문, 김민호, 문재창

초록

황과 가황촉진제 함량을 달리하여 배합한 고무와 황동 (Cu/Zn)또는 삼성분 합금 (Cu/Zn/Ni)이 피복된 강선코드의 접착을 조사하였다. 황과 가황촉진제 함량, 강선코드의 피복물질, 노화처리가 접착에 미치는 영향을 분산분석법을 적용시켜 고찰하였다. 황과 가황촉진제 함량이 모두 적거나 과다한 배합고무보다는 황과 가황촉진제 함량이 각각 6.0과 0.6phr인 배합고무에서 접착상태가 우수하였다. 가황촉진제와 노화처리사이에는 상호작용이 존재하며, 가황촉진제 함량이 많은 고무에서 접착 노화 현상이 두드러졌다. 황동이 피복된 강선코드에 비해 삼성분 합금이 피복된 강선코드에서 노화에 대한 안정성이 높았다.

Adhesion between compounding rubber and steel cord coated with either Cu/Zn or Cu/Zn/Ni alloy was investigated for varying amounts of sulfur and accelerator in the rubber compounds, by the method of analysis of variance. Good adhesion was obtained for the compound containing 6.0phr of sulfur and 0.6phr of accelerator. In addition, aging in adhesion was accelerated with increasing concentration of accelerator in the compound. The ternary alloy (Cu/Zn/Ni)-coated steel cords showed better stability in adhesion during aging than the brass(Cu/Zn)-coated steel cords.

[References]

Buchan S, "Rubber to Metal Bonding," Crosby Lockwood & Son, London (1959)
Hicks AE, Lyon F, Adhes. Age, 21 (1969)
vanOoij WJ, Rubber Chem. Technol., 52, 605 (1979)
Ayerst RC, Rodger ER, Rubber Chem. Technol., 45, 1497 (1972)
Albrecht KD, Rubber Chem. Technol., 46, 981 (1973)
Barker LR, Bristow GM, Rubber Chem. Technol., 54, 797 (1981)
Buswell AG, Eaton DC, Tidswell CR, Rubber World, 35 (1975)
Heamers G, Rubber World, 26 (1980)
Ramovist LH, Grinder NO, Sporrong M, Enghag P, Br. Patent, 1,444,886 (1975)
Ball JJ, Elastomer, 16 (1987)
Seo G, Kang SY, Kim MH, HWAHAK KONGHAK, 29(1), 97 (1991)
Seo G, Kim MH, Jeon GS, Oh SC, Noh IK, HWAHAK KONGHAK, 28(1), 77 (1990)
박성현, "현대실험계획법," 민영사 (1990)
Fielding-Russel GS, Livingston DI, Nicholson DW, Rubber Chem. Technol., 53, 950 (1980)
"The Vanderbilt Rubber Handbook," p. 589, R.O. Babbit Ed., R.T. Vanderbilt Company, Inc. (1978)
vanOoij WJ, Surf. Technol., 6, 1 (1977)
Erickson DE, Rubber Chem. Technol., 47, 213 (1974)

[Referenced By]

[1] Buchan S, "Rubber to Metal Bonding," Crosby Lockwood & Son, London (1959)

[2] Hicks AE, Lyon F, Adhes. Age, 21 (1969)

[3] vanOoij WJ, Rubber Chem. Technol., 52, 605 (1979)

[4] Ayerst RC, Rodger ER, Rubber Chem. Technol., 45, 1497 (1972)

[5] Albrecht KD, Rubber Chem. Technol., 46, 981 (1973)

[6] Barker LR, Bristow GM, Rubber Chem. Technol., 54, 797 (1981)

[7] Buswell AG, Eaton DC, Tidswell CR, Rubber World, 35 (1975)

[8] Heamers G, Rubber World, 26 (1980)

[9] Ramovist LH, Grinder NO, Sporrong M, Enghag P, Br. Patent, 1,444,886 (1975)

[10] Ball JJ, Elastomer, 16 (1987)

[11] Seo G, Kang SY, Kim MH, HWAHAK KONGHAK, 29(1), 97 (1991)

[12] Seo G, Kim MH, Jeon GS, Oh SC, Noh IK, HWAHAK KONGHAK, 28(1), 77 (1990)

[13] 박성현, "현대실험계획법," 민영사 (1990)

[14] Fielding-Russel GS, Livingston DI, Nicholson DW, Rubber Chem. Technol., 53, 950 (1980)

[15] "The Vanderbilt Rubber Handbook," p. 589, R.O. Babbit Ed., R.T. Vanderbilt Company, Inc. (1978)

[16] vanOoij WJ, Surf. Technol., 6, 1 (1977)

[17] Erickson DE, Rubber Chem. Technol., 47, 213 (1974)