Experiments are conducted to investigate the effect of system pressure, Ca/S ratio and primary air velocity on sulphur capture in a pressurized circulating fluidized bed (PCFB) combustor. The pressure inside the PCFB combustor is varied from 200 to 700 kPa. The Ca/S ratio is varied from 1.6 to 3.0. The primary air velocity ranges from 3 to 7 in s(-1). The bed temperature is maintained at 750 degreesC. The sulphur capture increases with system pressure in the present range of experimental investigations. The sulphur capture also increases with Ca/S ratio up to a certain ratio and then shows a decreasing trend for the given operating conditions. A semi-empirical model is developed for explaining the sulphur capture mechanism in the pressurized circulating fluidized bed combustor under batch combustion conditions. The experimental data are validated with the model predictions and a reasonable agreement has been observed. Copyright (C) 2002 John Wiley Sons, Ltd.