Electrochimica Acta, Vol.44, No.14, 2463-2472, 1999
The study of the electrooxidation of chloride at RuO2/TiO2 electrode using CV and radiotracer techniques and evaluating by electrochemical kinetic simulation methods
The mechanism of the chloride electrooxidation was investigated by CV and radiotracer techniques, as well as PC simulation methods on RuO2/TiO2 mixed oxide electrodes. The voltammetric behavior of an adsorbed intermediate was studied. Both the experimental and simulation results show that the electrooxidation of chloride is going through the steps of the Volmer-Heyrovsky mechanism on this working electrode.
Keywords:SURFACE-REACTIONS DRIVEN;LINEAR POTENTIAL SWEEP;ANODIC CL-2EVOLUTION;COMPUTER-SIMULATION;OXIDE;INTERMEDIATE;ADSORPTION;BEHAVIOR;MECHANISM