Electrochimica Acta, Vol.44, No.26, 4753-4762, 1999
Chronoamperometry of prussian blue films on ITO electrodes: ohmic drop and film thickness effect
The chronoamperograms associated with the reduction of prussian blue films deposited onto indium tin oxide (ITO) electrodes to the Everitt's salt form, are influenced by the ohmic drop effect. These chronoamperometric curves have been simulated by means of a numerical finite difference model which is able to explain their shape and their dependence on the thickness of the film and on the uncompensated resistance. An analytical expression which describes the dependence of current against time at initial times considering the ohmic drop effect has also been proved when applied to these chronoamperometric curves at short times.
Keywords:ELECTROCHEMICAL PREPARATION METHOD;IRON HEXACYANOFERRATEFILMS;MIXED-VALENCE HEXACYANIDES;THIN-FILMS;REDUCTION;ELECTROCHROMISM;POLYPYRROLE;OXIDATION;STABILITY;BEHAVIOR