Aramid 단섬유 보강 에폭시 복합재료 제조: 2. 에폭시 매트릭스의 경화촉진 영향 및 아라미드 섬유 보강 에폭시 복합 재료의 기계적 물성

임승하; 하창식; 조원제

Polymer(Korea), Vol.16, No.2, 216-224, March, 1992

Short Aramid Fiber reinforced Epoxy Composites : 2. Effect of Curing Acceleration of Epoxy Matrix and Mechanical Properties of Aramid Fiber Reinforced Epoxy Composites

임승하, 하창식, 조원제

초록

에폭시-아민계의 경화 촉진과 에폭시 매트릭스 및 아라미드 섬유보강 에폭시 복합재료의 기계적 물성에 미치는 에폭시 매트릭스의 경화촉진제의 영향을 연구하였다. 비스페놀A의 디글리 시딜에테르(DGEBA)는 촉진제와 함께/또는 촉진제 없이 메틸렌디아닐린(MDA)으로 경화시켰다. 본 연구를 위하여 트리스(디메틸아미노메틸)페놀(DMP-30)과 3-(3,4-디클로로페닐)-1,1-디메틸우레아(DIURON) 두 종류의 촉진제를 사용하였다. DMP-30이 높은 T_g와 빠른 겔화시간, 높은 기계적 강도를 보여 DIIUON보다 양호한 촉진제임을 알 수 있었다. 아라미드 섬유로 보강된 에폭시아민 복합재료에서도 DMP-30으로 경화 촉진된 에폭시 복합재료가 DIURON으로 경화 촉진된 에폭시 복합재료보다 높은 기계적 강도를 나타내었다.

The effect of curing accelerators on the mechanical properties of epoxy matrix and aramid fiber reinforced epoxy composites was investigated. The epoxy, diglycidylether of bisphenol A (DGEBA) was cured with methylene dianiline(MDA) with or without accelerators. Two kinds of accelerators were tested for the study ; tris(dimethylaminomethyl) phenol (DMP-30) and 3-(3,4-dichlorophenyl)-1,1-dimethyl urea (DIURON). DMP-30 is more effective accelerator than DIURON which showed higher T_g, faster gel time and good mechanical strength. In the aramid-fiber reinforced epoxyamine composites, it was also found that the composite accelereted by DMP-30 exhibits higher mechanical strength than that accelerated by DIIRON.

[References]

Tanaka Y, Bauer RS, "Curing Keactions," in C.A. May, ed., "Epoxy Resins Chemistry and Technology," 2nd ed., Chap. 3, Marcel Dekker Inc., New York (1988)
Lim SH, Ha CS, Cho WJ, Proc. Int'l Meeting on Rheology and Polymer Processing, Sept. 27-29, Seoul, pp. 199-201 (1990)
Shim JS, Lee W, Jang JS, Proc. Polym. Soc. Kor., '90 Annual Fall Meeting, pp. 86-87 (1990)
Dusek K, Polymer, 19, 931 (1978)
Gu J, Narang SC, Pearce EM, J. Appl. Polym. Sci., 30, 299 (1985)
Penn L, Newey HA, Chiao TT, J. Mater. Sci., 11, 190 (1976)
Penn L, Northolt MG, Eur. Polym. J., 10, 799 (1974)
"Kevlar 49 Data Manual," Dupont de Nemours Chemical Co., Delaware (1974)
Shim JS, Lee W, Jang JS, Polym. Bull., 25(6), 657 (1991)
Shim JS, Lee W, Jang JS, Polym. Bull., 25(6), 661 (1991)
Shim JS, Lee W, Jang JS, Polym. Bull., 25(6), 669 (1991)
May CA, "Epoxy Resins-Chemistry and Technology," 2nd ed., p. 505, p. 1093, Marcel Dekker Inc., New York (1988)
Gillham JK, Polym. Eng. Sci., 26(20), 1429 (1986)
Kim DH, Kim SC, Polym. Bull., 21, 121 (1989)
Noordam A, Wintraeken JM, Walton G, "Mechanical and Physical Properties of Epoxy Matrices as a Function of the Degree of Cure," in B. Sedlacek and J. Kahove, eds., "Crosslinked Epoxies," Proc. of 9th Disc. Conf., Prague, Caechoslovakia, July 14-17, p. 373 (1986)
Gillham JK, "Developments in Polymer Characterizations," Chap. 5, Appl. Sci. Publ., U.K. (1982)
Enns JB, Gillham JK, J. Appl. Polym. Sci., 28, 2831 (1983)
Donnellan T, Roylance D, Polym. Eng. Sci., 22, 821 (1982)
Choi CH, Ok YS, Kim BK, Polym.(Korea), submitted (1991)
Chiao TT, Wells JE, Moore RL, Hamstad MA, "Stress-Rupture Behavior of Strands of an Organic Fiber/Epoxy Matrix," ASTM, Standard Testing Procedure, ASTM STP-546, 209 (1974)
Busell AR, J. Mater. Sci., 10, 1300 (1975)
Clements LL, Moore RL, SAMPE Quart., 9(1), 6 (1977)
Hanson MP, "Effect of Temperature on the Tensile and Creep Characteristics of PRD-49 Fiber/Epoxy Composites," Nat'l. Aer. Space Admin, Tech. Memo. X 68053 (1972)
Chiao CC, Moore RL, Chiao TT, Composites, 161 (1977)
Chiao TT, Hamstad MA, "High-Performance Vessels from an Aromatic Polyamide Fiber/Epoxy Composite," Proc. Conf. Comp. Mat'ls., Geneva, Switzerland and Boston, Massachussetts, April 7-11 and 14-18, vol. 2, p. 365 (1975)
Blumentritt BF, Vu BT, Cooper SL, Composites, 107 (1975)

[Referenced By]

[1] Tanaka Y, Bauer RS, "Curing Keactions," in C.A. May, ed., "Epoxy Resins Chemistry and Technology," 2nd ed., Chap. 3, Marcel Dekker Inc., New York (1988)

[2] Lim SH, Ha CS, Cho WJ, Proc. Int'l Meeting on Rheology and Polymer Processing, Sept. 27-29, Seoul, pp. 199-201 (1990)

[3] Shim JS, Lee W, Jang JS, Proc. Polym. Soc. Kor., '90 Annual Fall Meeting, pp. 86-87 (1990)

[4] Dusek K, Polymer, 19, 931 (1978)

[5] Gu J, Narang SC, Pearce EM, J. Appl. Polym. Sci., 30, 299 (1985)

[6] Penn L, Newey HA, Chiao TT, J. Mater. Sci., 11, 190 (1976)

[7] Penn L, Northolt MG, Eur. Polym. J., 10, 799 (1974)

[8] "Kevlar 49 Data Manual," Dupont de Nemours Chemical Co., Delaware (1974)

[9] Shim JS, Lee W, Jang JS, Polym. Bull., 25(6), 657 (1991)

[10] Shim JS, Lee W, Jang JS, Polym. Bull., 25(6), 661 (1991)

[11] Shim JS, Lee W, Jang JS, Polym. Bull., 25(6), 669 (1991)

[12] May CA, "Epoxy Resins-Chemistry and Technology," 2nd ed., p. 505, p. 1093, Marcel Dekker Inc., New York (1988)

[13] Gillham JK, Polym. Eng. Sci., 26(20), 1429 (1986)

[14] Kim DH, Kim SC, Polym. Bull., 21, 121 (1989)

[15] Noordam A, Wintraeken JM, Walton G, "Mechanical and Physical Properties of Epoxy Matrices as a Function of the Degree of Cure," in B. Sedlacek and J. Kahove, eds., "Crosslinked Epoxies," Proc. of 9th Disc. Conf., Prague, Caechoslovakia, July 14-17, p. 373 (1986)

[16] Gillham JK, "Developments in Polymer Characterizations," Chap. 5, Appl. Sci. Publ., U.K. (1982)

[17] Enns JB, Gillham JK, J. Appl. Polym. Sci., 28, 2831 (1983)

[18] Donnellan T, Roylance D, Polym. Eng. Sci., 22, 821 (1982)

[19] Choi CH, Ok YS, Kim BK, Polym.(Korea), submitted (1991)

[20] Chiao TT, Wells JE, Moore RL, Hamstad MA, "Stress-Rupture Behavior of Strands of an Organic Fiber/Epoxy Matrix," ASTM, Standard Testing Procedure, ASTM STP-546, 209 (1974)

[21] Busell AR, J. Mater. Sci., 10, 1300 (1975)

[22] Clements LL, Moore RL, SAMPE Quart., 9(1), 6 (1977)

[23] Hanson MP, "Effect of Temperature on the Tensile and Creep Characteristics of PRD-49 Fiber/Epoxy Composites," Nat'l. Aer. Space Admin, Tech. Memo. X 68053 (1972)

[24] Chiao CC, Moore RL, Chiao TT, Composites, 161 (1977)

[25] Chiao TT, Hamstad MA, "High-Performance Vessels from an Aromatic Polyamide Fiber/Epoxy Composite," Proc. Conf. Comp. Mat'ls., Geneva, Switzerland and Boston, Massachussetts, April 7-11 and 14-18, vol. 2, p. 365 (1975)

[26] Blumentritt BF, Vu BT, Cooper SL, Composites, 107 (1975)